- B. F. Garrett Account Book, 1842/18491
- Board of Visitors records, 1757/20231
- Carter Family Papers, 1667/1862, bulk 1792/18611
- Charles Brown Papers, 1792/18881
- Duff Green Letter, 18411
- Early Records of the Mount Vernon Ladies' Association, 1853/1951, bulk 1853/18754
- James Semple's Views on Promoting the Good of the College, 18251
- John Buchanan Floyd Papers, 1831/18621
- John Jordan Crittenden Letter to John Bell, 18411
- John Tyler Letter to Benjamin Ogle Tayloe, 18351
- John Tyler Letter to Henry A. Wise, 18551
- John Tyler Letter to Robert S. Stanard, 18191
- John Tyler Papers, 1840/19311
- John Tyler daguerreotype, 18441
- Jonathan M. Bennett (1816-1887) Papers, 1785/18991