- Cabell Family Papers, 1693/1913, bulk 1743/18231
- Carter Lowance Papers, 1860/1993, bulk 1942/19881
- Charles Triplett O'Ferrall Papers, 1856/1904, bulk 1867/18931
- David McKinney Papers, 1977/20131
- Fitzhugh Lee Papers, 1866/18871
- Governors Conference Records and Exhibit, 19571
- Henry Alexander Wise Letter to Robert S. Chilton, 18391
- Henry Alexander Wise Papers, 1856/18591
- Jeffery Amherst Commission as Virginia Governor, 17591
- John Buchanan Floyd Papers, 1831/18621
- John Dalton Papers, circa 1978-1982, 1978/19821
- John Garland Pollard Papers, 1683/1968, bulk 1856/19371
- Marriage Settlement of the Earl and Countess of Orkney, 16951
- Mills E. Godwin, Jr. Papers, 1712/1989, bulk 1947/19891
- Tazewell Family Papers, 1797/18501