- W. Dale Parker Papers, 1914/200666
- WCWM records, 1938/2024, bulk 1970/200811
- WLR Foods records, 1948/20025
- WLUR Recordings and Broadcasts, 1938/20108
- WV FREE Records, 1993/20105
- Walker-Wood families papers, 1798/2019, bulk 1900/19708
- Walter H. Ryland Briefs, 1968/20081
- Walter Taylor Reveley II collection, 1917/19926
- Walter and Osie Lewis Family Papers, 1908/20062
- Ware River Circle of the King's Daughters Records, 1912/20161
- Warren Chappell papers, 1929/20001
- Warren Witschey, Compiler, Magnolia High School Football Records and Other Materials, 1893/2022, bulk 1902/20214
- Washington Office Records, 2000/20101
- Washington and Lee University School of Law Collection, 1859/20021
- Washington and Lee University and Regional Virginia History Research Collection, 1609/201613