- Audio Visual Collection, 1928/20153
- Barbara Lustbader New York City playbills collection, 1957/20123
- Barbara Woodward Architectural Collection, 1966/19922
- Barnette Collection, Lawyer, Businessman, Educator, Philanthropist, and Chairman Emeritus of Bethlehem Steel Corporation, 1905/20203
- Benjamin L. Wigfall Artist Archives and Mary Carter Wigfall Personal Papers, 1880/202331
- Beverly Randolph Middleton Papers, 1938/19841
- Beverly Willis Architectural Collection, 1954/19996
- Blacksburg Baptist Church Records, 1894/20074
- Board of Visitors Records, 1920/20104
- Bob Bersson Papers, 1981/20172
- Breece D'J Pancake papers, 1973/20131
- Bruton Parish Church (Williamsburg, Va.) records, 1662/2010, bulk 1900/20002
- Calvert Walke Tazewell Papers, 1900/19974
- Carolyn Rhodes Papers, 1924/201912
- Carter/Cash Family Collection, 1940/20092