- A.J. Morrison Collection, 1754/19751
- Ancient Coins, 1956/19933
- Dr. Charles Ferguson McRae Collection, 1935/19931
- Dr. Herbert J. Sipe, Jr. Papers, 1927/201919
- Dr. Walter Taylor Reveley II Papers, 1963/19933
- Elizabeth Carrington Eggleston Papers, 1899/19944
- Hampden-Sydney College Photograph Collection, 17756
- Hampden-Sydney Diploma Collection, 1775/19742
- Hampden-Sydney Library Records, 1930/20124
- Josiah Bunting III Papers, 1972/19982
- Log Cabin School Collection, 1966/20222
- Paul L. Grier Vertical Files, 1775/19882
- Prince Edward County Integration Collection, 1943/19754
- Records of the Merrill's Marauders Proud Descendants Association, 1944/202012
- Records of the Philanthropic, Union, and Union-Philanthropic Literary Societies, 1789/20072