- Adele Blow Chatfield-Taylor family papers, 1899/19773
- Adele Goodman Clark papers, 1849/19789
- Albert L. Sturm Papers, 1904/19881
- Alexander Haight family collection, 1764/19761
- Alexandria Library Records (MS098), 1937/20134
- Alfred C. Payne Collection, 1917/20031
- Alleghany Chapter, National Society of the Daughters of the American Revolution Records,, 1890/20221
- Alumni Association Records, 1833/2014, bulk 1950/200510
- Alumni Association Records, 1924/20161
- American Association of University Women (AAUW) Records, Harrisonburg, Virginia Branch, 1929/20252
- American Association of University Women, Norfolk Branch (AAUW) Records, 1902/20003
- Ancella Bickley, Historian, Research Papers regarding African-Americans, 1775/2018, bulk 1970/201113
- Archive of Virginia Composers, 1931/19792
- Armistead Boothe Papers (MS164), 1803/19903
- Arthur E. Scott photograph collection14