- Adele Blow Chatfield-Taylor family papers, 1899/19772
- Adele Goodman Clark papers, 1849/19783
- Alexander Farish Robertson Papers, 1867/19316
- Alexander Haight family collection, 1764/19761
- Alumni Association Records, 1833/2014, bulk 1950/20053
- American Association of University Women, Norfolk Branch (AAUW) Records, 1902/20001
- Ancella Bickley, Historian, Research Papers regarding African-Americans, 1775/2018, bulk 1970/201111
- Armistead Boothe Papers (MS164), 1803/19902
- Austin-Twyman Papers, 1765/193919
- Bailey-Law Collection, 1825/19715
- Bell, Kent, Cloyd, Withrow Family Collection, 1780/19981
- Benjamin A. Banks Papers, 1855/19748
- Benjamin L. Wigfall Artist Archives and Mary Carter Wigfall Personal Papers, 1880/20231
- Black, Kent, and Apperson Family Papers, 1779/19847
- Blacksburg Baptist Church Records, 1894/20074