- Ancella Bickley, Historian, Research Papers regarding African-Americans41
- Andrew Delmar Hopkins (1857-1948) Papers1
- Andrew Delmar Hopkins Papers1
- Andrew Nelson Campbell (d.1919) Papers1
- Andrew Nelson Campbell Papers1
- Andrew Nelson Campbell, Civil War Veteran and Monroe County Politician, Papers1
- Andrew S. Core, Typescripts and Charts1
- Anita Cutright Burnett, Collector, Papers1
- Anna Jarvis (1864-1948) Papers2
- Anthony Ware, Miscellaneous Papers1
- Appalachian Prints Collection10
- Arah J. Evans Autograph Album1
- Archibald W. Campbell (1839-1899), Newspaperman, Papers3
- Aretas Brooks Fleming (1839-1923) Papers2
- Aretas Brooks Fleming Papers1