- W. Jett Lauck papers, 1900/19522
- Wade Hampton Frost papers, 1880/19845
- Waller family papers, 1677/19651
- Washington and Lee University and Regional Virginia History Research Collection, 1609/20162
- West Virginia Naturalization Records, 1814/19911
- Wickham family papers, 1704/19502
- William Booth Taliaferro Papers, 1811/19542
- William Cole Collection of Documents Pertaining to the Colonial-Era, 1676/1971, bulk 1730/17701
- William Munford Tuck Papers, 1918/19681
- Williamsburg (Va.) Area Ephemera Collection, 1858/20151
- Willis Guy Tetrick, Jr. Genealogy Research Papers, 1708/19972
- Wilson-Lewis Family Papers, 1693/19421
- Women's Volleyball records, 1976/20081