- Anatole and Vladimir Kalichevsky Papers, 1871/19551
- Anderson Family papers, 1755/19581
- Anne T. Chapman Papers, 1884/19541
- Arthur M. Squires Papers, 1888/1987, bulk 1940/19871
- Arthur W. and Leah James Scrapbooks, 1909/19771
- Association for the Preservation of Virginia Antiquities, Colonial Capitol Branch Records, 1896/19891
- Association for the Preservation of Virginia Antiquities, Yorktown Branch Records, 1921/2013, bulk 1975/20051
- Ball Family Papers, 1887/19761
- Barbara Cary Johnston Willard Scrapbook, 1800/20061
- Bernice Jones Smith photograph album, 1930/19391
- Betty Brown Clemmer and Willis Clemmer papers, 1920/2015, bulk 1943/19491
- Blackley Family papers, 1830/20201
- Blacksburg Baptist Church Records, 1894/20071
- Blake T. Newton, Jr. Papers, 1939/19851
- Bland Family papers, 1778/19891