- Audie Scott Tilghman papers, 1925/19301
- Audrey Brubeck letters, 1963/19641
- Audrey Hatcher Vaughan papers, 1942/19441
- August R. Offer, Jr. Papers, 1945/19461
- Autographs of Virginians, 1846/19081
- Barbara McKnight Benham papers, 1966/20211
- Barney Baker papers, 1944/19451
- Barnhart Family Papers, 1836/19441
- Baron de Watergeul Boom Letter, 17811
- Barton Myers Papers, 1878/19251
- Benjamin Bray Papers, 1950/1999, bulk 1985/19951
- Bertha Couchman Hess and Ethel Virginia Dunn Correspondence, 1918/19271
- Bettie Hiter Willis Papers, 1864/19421
- Betty Brown Clemmer and Willis Clemmer papers, 1920/2015, bulk 1943/19491
- Bishop James Madison Letter to the Speaker of the House of Delegates concerning Eastern State Hospital, 17881