- Alumni and VMI certificates and citations collection, 1860/20131
- Amos Koontz Papers I, 1809/1965, bulk 1936/19651
- Anatole and Vladimir Kalichevsky Papers, 1871/19551
- Blackley Family papers, 1830/20201
- Board of Visitors appointment documents, 1839/19301
- Carter Lowance Papers, 1860/1993, bulk 1942/19881
- Charles Edward Gary, Jr. Papers, 1870/2000, bulk 1940/19801
- Davis, Kline, and Hutton Family papers, 1816/19771
- Dora and Cara Armistead Papers, 1880/19501
- Edward Belvin Collection of Williamsburg and James City County materials, 1874/19871
- Grigsby-Galt Papers, 1736/1982, bulk 1840/19301
- Hall Family Papers, 1810/20071
- Hart Papers I and II, 1847/19341
- John F. Bransford papers, 1865/19161
- John Frederick Pierson Papers, 1864/19251